The use of beta-carotene as environmentally safe inhibitor for Cu-Al-Ni alloyscorrosion in sulfide polluted chloride solutions

Abstract

The stability of Cu-Al-Ni alloys used in the manufacture of NaCl in Egypt was investigated in sulfide polluted chloride solutions. Three different alloys, namely, Cu-10Al-5Ni, Cu-10Al-10Ni and Cu-10Al-45Niwereinvestigatedinchloride containingsulfide^-ions using different electrochemical techniques including polarization and electrochemical impedance spectroscopy. The presence of sulfide ions in the chloride solution accelerates thecorrosion of Cu-Al-Ni alloys,whereas the increase of the nickel content in the alloy improves its corrosion resistance.?-carotene as eco-friendly corrosion inhibitor was used to protect the Cu-10Al-Ni alloys from corrosion in presence of sulfide ions. The corrosion inhibition efficiency reached >95% at 50 ppm of ?-carotene. The alloy surface was investigated by the scanning electron microscope and the surface constituents were analyzed by EDAX.

Keywords: Corrosion; chloride, Cu-Ni alloys; EIS; sulfide pollution.