Solar Energy Conversion and Storage: Rose Bengal-Triton X-100 by Photogalvanic Cell

Abstract

Photogalvanic cells are photoelectrochemical devices involving ions as mobile charges moving in solution through diffusion process. These cells are capable of solar power generation at low cost with inherent storage capacity. This property of photogalvanic cell needs to be exploited as this technology is cleaner and promising for application in daily life. In our work, Rose Bengal is used as photosensitizer with oxalic acid as reductant and triton as surfactant for photoelectrochemical conversion of solar energy into electrical energy. The photopotential and photocurrent generated were 289.0 mV and 29.1 µA, respectively. The maximum power of the cell was 8.409 µW. The observed conversion efficiency was 0.023 % and fill factor was determined as 0.293 against the maximum theoretical value 1.0. The photogalvanic cell can work for 45.0 min in dark after irradiation for 21.0 min, i.e. the storage capacity of the photogalvanic cell is 45 min. The effect of different parameters on electrical output of the cell was studied and a mechanism has also been proposed for the generation of photocurrent in photogalvanic cell.

Keywords: Rose Bengal; Oxalic acid; Triton; Conversion efficiency; Storage capacity; Photocurrent.