Effect of Activation Method and Agent on the Characterization of Prewinkle Shell Activated Carbon
Abstract
The effect of activation method (physical and chemical) and the concentration of the chemical activating agents on the characterization of periwinkle shell activated carbon was investigated. The periwinkle shell was pyrolysed and activated by physical activation (using an oxidizing gas - steam) and chemical activation (using base: ZnCl2, CaCl2 and acid: H2SO4, HCl). The produced activated carbons were characterized to determine the bulk density, moisture content, pore volume, porosity, ash content, iodine number and surface area following standard ASTM procedures. The effects of concentration of the activating agents on these properties were also studied. Effects of activation method on activation carbon properties showed that the chemical activated carbon had higher bulk density, pore volume, porosity, ash content, iodine number, and surface area, while the physical activated carbon had higher moisture content. The effect of activating agent concentration showed that the bulk density, pore volume and porosity increased with concentration for base activated carbon and decreased with concentration for acid activated carbon. The ash content and iodine number fluctuated (initial increase then decrease and increase) for base activated carbon; while these parameters increased continuously and fluctuated (initial decrease the continuous increase) with concentration for acid activated carbon. The moisture content and surface area decreased with concentration for base activated carbon; these parameters fluctuated (initial increase, decrease then increase) and increased continuously for acid activated carbon. Periwinkle shell carbon chemically activated with ZnCl2 was the best activated carbon with highest density, pore volume, porosity, iodine number and surface area.
Keywords: Activated carbon, Physical and Chemical activation, effect of activation agent concentration.
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ISSN (Paper)2224-7467 ISSN (Online)2225-0913
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