Characterisation of Agbabu Natural Bitumen and Its Fractions Using Fourier Transform Infrared Spectrometry

Abstract

Physico-chemical characterization of bitumen is very germane to its applications. There have been many physico-chemical investigations on Agbabu natural bitumen (ANB), but there appears to be some discrepancies in the results of some of the findings. Thus, the need to re-examine some of the physico-chemical parameters of the ANB. Raw sample of ANB was obtained from one of the observatory wells in Agbabu, Ondo State, Nigeria. The sample was dehydrated, purified and asphaltene component precipitated through addition of n-pentane to the sample. The maltene component was fractionated into saturate, aromatics and resin using column chromatographic method. The purified ANB sample and its fractions were each subjected to infrared analysis. In addition, the elemental composition and trace metals in the whole purified ANB were quantified using CHNS-O Analyzer (FlashEA® 1112) and Atomic Absorption Spectrometer (AAS) respectively. Infrared spectral features obtained for the whole bitumen and its fractions bear a good degree of resemblance to the results of earlier workers on the subject with some minor differences. The values obtained for structural indexes from Infrared (IR) spectra showed that all the fractions contained branch and straight chain hydrocarbons. The structural indexes also showed that asphaltenes and resin fractions are strongly polar, both of which contain hetero–atomic compounds. Results of compositional analysis are: C (86.62%), H(10.98%), S (0.92%) N (0.48%), O (0.83%), Maltene (78.34%) aand Asphaltene (21.67%). The concentrations of the trace metals are: Mg (792.00 ppm), Mn (28.40 ppm), Fe (3633.10 ppm), Ca (1082.10 ppm), Zn (17.50 ppm), Cu (17.90 ppm), Cr (153.90 ppm), Pb (93.78 ppm), Ni (103.65 ppm), V (156.53 ppm) and Na (3740.00 ppm). Results of compositional and trace metals analyses of this study are at variance with the earlier results on characterization of ANB in the literatures. The differences in the results might be attributed to variation in the method of sample preparation especially the inclusion of dehydration of the raw ANB in the purification step prior to characterization as introduced in this study. Keywords: Aromatics, Asphaltenes, Agbabu Natural Bitumen, IR, Resins, Saturates