Use of 5-[2-Ethoxyquinazolone-3-yl]-2-phthalimidomethylthiadiazole in the Synthesis of N- and C-Glycosides via Amadori Rearra
Abstract
Synthesis of novel 5-[2- aminoquinazolin-4-one-3-yl]-2- phthalimidomethylthiadiazole   2 from  5-[2-ethoxyquinazolin-4-one-3-yl]-2-phthalamidomethylthiadiazole. The behavior of as a nitrogen nucleophile towards an ±-hydroxy-aldehyde,  such as glucose and formation of Amadori rearrangement product (ARP) that has had occurred during the course of reaction was discussed.
Keywords: N-Glycosides, ±-bromoglucose, Amadori rearrangement, quinazolinone
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ISSN (Paper)2224-3224 ISSN (Online)2225-0956
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